Ma, S. Herzon, J. The protocol offers use of readily available starting materials and broad substrate scope. Zeng, H. Sajiki, S. Cui, Org. Karimi, J. Rajabi, Synthesis , , In the presence of hydrogen peroxide and trimethylsilyl chloride, thiocarbonyls desulfurize to the corresponding carbonyls in short reaction times with no side reactions and excellent selectivity.
This process is a safe, operationally simple, and environmentally benign alternative for the desulfurization of thiocarbonyls. Bahrami, M. Khodaei, M. Tajik, Synthesis , , The oxidation of malononitrile derivatives with peracid in methanol proceeds with loss of the cyano groups to yield methyl esters in high yield. The method was applied to a variety of malononitrile derivatives, some of which were prepared by Pd- or Ir-catalyzed asymmetric allylic substitution.
Tverskoy, G. Helmchen, Synlett , , Xie, S. Majji, S. Rajamanickam, N. Khatun, S. Santra, B. Patel, J. An efficient oxidation of cyclic acetals provided hydroxy alkyl esters in good yields in the presence of MCPBA. Kim, H. Rhee, M. Kim, J. Korean Chem.
CrO 3 is an efficient catalyst for benzylic oxidation with periodic acid as the terminal oxidant in acetonitrile. Substituted electron-poor toluenes and diarylmethanes were oxidized to the corresponding substituted benzoic acids and ketones in excellent yields.
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Pure Liquids: Extended Data. Part 2 pp. Improve this question. Add a comment. Active Oldest Votes. Improve this answer.
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